Dr. Khalili Directory


 

                                                                                                                                                                                                         

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Dariush Khalili

Assistant Professor

Office: A-310 Department of Chemistry

Phone: +98 713 613 7113

Email: khalili@shirazu.ac.ir

 

Education

 

-B.Sc. in Pure Chemistry, Persian Gulf University (1999-2003), Shiraz, Iran.

-M.Sc. in Organic Chemistry, Shiraz University (2003-2005), Shiraz, Iran.

  • Thesis: Synthesis of new mono and bis spiro β-lactams
  • Advisor: Prof. Ali Asghar Jarrahpour, Dept. of Chemistry, Shiraz University,* Shiraz, Iran

*Chem. Dept. of Shiraz University is the leading Chem. Dept. in the field of Catalyst in the     nation

-Ph.D. in Organic Chemistry, Shiraz University (2005-2010), Shiraz, Iran.

  • Thesis: Aromaticazocompoundsasnewreagentsin Mitsunobuchemistryandtheirapplicationsinorganicchemistry
  • Advisors: Prof. Nasser Iranpoor and Prof. Habib Firouzabadi, Dept. of Chemistry, Shiraz University, Shiraz, Iran

 

 

Research Interests

Use of Carbonaceous Materials as Reagent for Organic Transformations

Selected Publications

 

  1. Dariush Khalili, Ali Reza Banazadeh, Elham Etemadi-Davan, Facile assemblies of palladium nanoparticles on amino-vinyl silica functionalized magnetic carbon nanotube with robust catalytic performance in the Suzuki-Miyaura coupling reaction, ChemPlusChem. 2016, submitted manuscript.
  2. Elham Etemadi-Davan, Nasser Iranpoor and Dariush Khalili, Pd-catalyzed one-pot benzimidazole formation from the reaction of aryl halides with o-diaminobenzene or o-nitroaniline through reductive carbonylation-ring closure reactions, Chem. Select. 2016, submitted manuscript.
  3. Dariush Khalili, Elham Etemadi-Davan, Ali Reza Banazadeh, Graphene oxide: a heterogeneous and metal-free carbocatalyst for arylation of benzothiazoles with aldehydes and benzylic alcohols using diisopropyl azodicarboxylate (DIAD) as oxidant, RSC Adv. 2016, accepted manuscript.
  4. Dariush Khalili, Graphene oxide: a reusable and Metal-Free Carbocatalyst for the one-pot synthesis of 2-amino-3-cyanopyridines in water, Tetrahedron Lett. 2016, 57, 1721-1723.
  5. Mohammad Abbasi, Dariush Khalili, Basic Al2O3 promotes onepot synthesis of thioethers via in situ generation and addition of β-acyloxy mercaptans to electron deficient alkenes. J. Iran. Chem. Soc. 2016, 13, 653-658.
  6. Dariush Khalili, Graphene oxide: a promising carbocatalyst for the regioselective thiocyanation of aromatic amines, phenols, anisols and enolizable ketones by hydrogen peroxide/KSCN in water. New J. Chem. 2016, 40, 2547-2553 .
  7. Dariush Khalili and Ali Reza Banazadeh, Graphene Oxide as a Heterogeneous Reagent Promoted Synthesis of 2-Substituted 1,3-Benzazoles in Water. 2015, 88, 1693-1706.
  8. Dariush Khalili, Nasser Iranpoor and Habib Firouzabadi, 4,4ʹ-Azopyridine as an easily prepared and recyclable oxidant for synthesis of symmetrical disulfides from thiols or alkyl halides(tosylates)/thiourea. J. Sulfur. Chem. 2015, 36, 544-555.
  9. Dariush Khalili, Graphene oxide assisted one-pot and odorless synthesis of symmetrical disulfides using alkyl halides and thiourea as sulfur source reagent. Phosphorus, Sulfur, and Silicon and the Related Elements, 2015, 190, 1727-1734.
  10. Dariush Khalili, H2O2/nanomagnetic Fe3O4 as a highly efficient, regioselective and eco-friendly system for the catalytic thiocyanation of activated arenes. Chin. Chem. Lett. 2015, 26, 547-552.
  11. Mohammad Abbasi and Dariush Khalili, Direct synthesis of disulfides from alkyl halides using thiourea and CCl4 in glycerol, J. Iran. Chem. Soc. 2015, 12, 1425-1430.
  12. Najmeh Nowrouzi, Dariush Khalili and Maryam Irajzadeh, One-pot synthesis of 1,2,4-oxadiazoles from carboxylic acids using 4-(dimethylamino)pyridinium acetate as efficient, regenerable, and green catalyst with ionic liquid character. J. Iran. Chem. Soc. 2015; 12, 801-806.
  13. Nasser Iranpoor; Habib Firouzabadi and Dariush Khalili,Heteroaromatic azo compounds as efficient and recyclable reagents for direct conversion of aliphatic alcohols into symmetrical disulfides. Tetrahedron Lett. 2012, 53, 6913.
  14. Nasser Iranpoor; Habib Firouzabadi, R. Shahin and Dariush Khalili, 2,2´-Azobenzothiazole as a New Recyclable Oxidant For Heterogeneous Thiocyanation of Aromatic Compounds with Ammonium Thiocyanate, Synth. Commun. 2012, 42, 2040.
  15. Nasser Iranpoor; Habib Firouzabadi and Dariush Khalili, The First Mitsunobu Protocol for Efficient Synthesis of α-Acyloxyphosphonates Using 4,4´-Azopyridine, Phosphorus, Sulfur, and Silicon and the Related Elements, 2011, 186, 2166.
  16. Nasser Iranpoor; Habib Firouzabadiand andDariush Khalili, 5,5′-Dimethyl-3,3′-azoisoxazole As A New Heterogeneous azo Reagent For Esterification of Phenols and Selective Esterification of Benzylic Alcohols Under Mitsunobu Condition, Org. Biomol. Chem. 20108, 4436-4443.
  17. Nasser Iranpoor; Habib Firouzabadi, Dariush Khalili and R. Shahin, A New Application for Diethyl azodicarboxylate: Efficient and Regioselective Thiocyanation of Aromatics Amines, Tetrahedron Letters, 2010, 51, 3508-3510.
  18. Nasser Iranpoor; Habib Firouzabadi and Dariush Khalili, New Heteroaromatic Azo Compounds Based on Pyridine, Isoxazole and Benzothiazole for Efficient and Highly Selective Amidation and Mono-N-Benzylation of Amines under Mitsunobu Conditions, Bull. Chem. Soc. Jpn. 2010, 83, 923-934.
  19. Nasser Iranpoor; Habib Firouzabadi, Najmeh Norouzi, and Dariush Khalili; Selective mono- and di-N-alkylation of Aromatic Amines With Alcohols and Acylation of Aromatic Amines Using Ph3P/DDQ, Tetrahedron, 2009, 65, 3893-3899.
  20. Nasser Iranpoor; Habib Firouzabadi, Dariush Khalili and Somayeh Motevalli, Easily Prepared Azopyridines as Potent and Recyclable Reagents for Facile Esterification Reactions. An Efficient Modified Mitsunobu Reaction, Journal of Organic Chemistry, 2008, 73,4882-4887.
  21. Ali Asghar Jarrahpour; Dariush Khalili; E, De Clercq; C, Salmi; J, Michel, Synthesis, Antibacterial, Antifungal and Antiviral Activity Evaluation of Some New Schiff Bases of Isatin and Their Derivatives, Molecules 2007, 12, 1720-1730.
  22. Ali Asghar Jarrahpour and Dariush Khalili; Synthesis of Some mono- and bis-Spiro-β-Lactams of Benzylisatin, Tetrahedron Letters, 2007, 48, 7140-7143.
  23. Ali Asghar Jarrahpour and Dariush Khalili; Synthesis of Some New bis-Schiff Bases of Isatin and 5-Fluoroisatin in a Water Suspension Medium, Molecules 2006, 11, 59-63.
  24. Mehmet Akkurt, Selvi Karaca, Ali Asghar Jarrahpour, Dariush Khalili and Orhan Büyükgüngör; 3-Phenoxy-1,4-diphenylazetidin-2-one, Acta Cryst. 2006, E62,o866-o868.
  25. Serife Pınar, Mehmet Akkurt, Ali Asghar Jarrahpour, Dariush Khalili and Orhan Büyükgüngör; 1′-Benzyl-1-(2,4-dimethoxyphenyl)-3-phenoxyspiro[azetidine-2,3′(3H)-indole]-2′,4(1H)-dione, Acta Cryst. 2006, E62, o804-o806.
  26. Mehmet Akkurt; Sevim Tuerktekin; Ali Asghar Jarrahpour; Dariush Khalili; Orhan Bueyuekguengoer.N-Benzylindole-2,3-dione (N-benzylisatin) , Acta Cryst. 2006, E62, o1575-o1577.
  27. Ali Asghar Jarrahpour, Dariush Khalili, Synthesis of 3-[(4-{3-[(2-oxo-1,2-dihydro-3H-indol-3-yliden)amino]phenoxy}phenyl)imino]-1H-indol-2-one as a novel Schiff base, Molbank 2005, M429.
  28. Ali Asghar Jarrahpour, Dariush Khalili; Synthesis of 3,3´-[methylenebis(3,1-phenylenenitrilo)]bis[1,3-dihydro]-2H-indol-2-one as a novel bis-Schiff base, Molbank 2005, M437.